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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D231-20
filingDate 1988-06-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_72494fe22e871d593cc4a8b38e3b3cc8
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publicationDate 1989-12-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H01316364-A
titleOfInvention Production of pyrazole benzoic acid esters
abstract PURPOSE: To readily and industrially advantageously obtain the subject compound useful for intermediate of herbicide in high yield by reacting substituted benzene with 5-hydroxypyrazoles and CO in co-existence of base and catalyst of VIII group in table of periodic law of elements. n CONSTITUTION: A substituted benzene expressed by formula I (X is Br, I or base of diazoniumtetrafuluoroboric acid; R 1 is 1-4C alkyl and alkoxy, OH, 3-6C alkoxyalkoxy or 2-5C alkoxyalkyl, etc.; R 3 is 1-2C alkylthio or alkylsulfinyl, CF 3 , NO 2 or halogen, etc.; with a proviso that R 1 -R 3 is F or C where X is Br; R 1 -R 3 is F, C or Br where X is I) is reacted with 5-hydroxypyrazoles expressed by formula II (A is 1-3C alkyl, allyl or propargyl; B is H or CH 3 ) and CO in co-existence of a base and a catalyst of VIII group in table of periodic law of elements to obtain the aimed compound expressed by formula III. n COPYRIGHT: (C)1989,JPO&Japio
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priorityDate 1988-06-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 29.