http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H01224345-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_f6e960aa6ad2ba6401030159343ebe68 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-52 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-78 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-83 |
filingDate | 1988-03-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b042cda706706f7efca4072693ba0c56 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_78773e53c1d6678f0006851d9f47964c |
publicationDate | 1989-09-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-H01224345-A |
titleOfInvention | Production of hydroxyaryl aryl ketones |
abstract | PURPOSE: To readily obtain the subject compounds which are an intermediate for dyes, etc., in high selectivity in one step, by reacting phenols with aromatic carboxylic acids in the presence of a specific polysiloxane catalyst and passing the resultant product through an ester compound. n CONSTITUTION: Phenols are reacted with aromatic carboxylic acids in the presence of a polysiloxane catalyst having sulfonated phenyl groups as a catalyst in an amount within the range of 10W90mol. based on 100mol. phenols, normally at 100W400°C, especially 150W350°C to provide an ester compound, which is then subjected to the Fries rearrangement to afford the aimed compounds. The above-mentioned catalyst used is obtained by adding and reacting alcohols and dilute hydrochloric acid with a mixture of a phenyltrialkoxysilane with a tetraalkoxysilane, etc., and sulfonating the resultant polysiloxane having phenyl groups. n COPYRIGHT: (C)1989,JPO&Japio |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-9910305-A1 |
priorityDate | 1988-03-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 29.