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filingDate 1988-03-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b042cda706706f7efca4072693ba0c56
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publicationDate 1989-09-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H01224345-A
titleOfInvention Production of hydroxyaryl aryl ketones
abstract PURPOSE: To readily obtain the subject compounds which are an intermediate for dyes, etc., in high selectivity in one step, by reacting phenols with aromatic carboxylic acids in the presence of a specific polysiloxane catalyst and passing the resultant product through an ester compound. n CONSTITUTION: Phenols are reacted with aromatic carboxylic acids in the presence of a polysiloxane catalyst having sulfonated phenyl groups as a catalyst in an amount within the range of 10W90mol. based on 100mol. phenols, normally at 100W400°C, especially 150W350°C to provide an ester compound, which is then subjected to the Fries rearrangement to afford the aimed compounds. The above-mentioned catalyst used is obtained by adding and reacting alcohols and dilute hydrochloric acid with a mixture of a phenyltrialkoxysilane with a tetraalkoxysilane, etc., and sulfonating the resultant polysiloxane having phenyl groups. n COPYRIGHT: (C)1989,JPO&Japio
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Total number of triples: 29.