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filingDate 1988-02-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e023023bf7c330ed353938863cb35f1f
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publicationDate 1989-08-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H01203346-A
titleOfInvention Production of 2-chloropropionaldehyde
abstract PURPOSE: To readily and efficiently obtain the present compound in high selectivity at a low temperature under a low pressure, by reacting vinyl chloride with CO and H 2 in the presence of a catalyst, such as a rhodium compound and trivalent organic phosphorus compound, coexisting with an organic acid and base as a cocatalyst. n CONSTITUTION: Vinyl chloride is reacted with CO and H 2 in the presence of a catalyst of a rhodium compound, such as hexadecanylhexarhodium, and a trivalent organic phosphorus compound, such as triphenylphosphine, or an oxide thereof coexisting with an organic acid, such as phthalic acid, and a base, such as NaOH, further in the presence of preferably water, preferably in a solvent, such as toluene, at 10W150°C under 10W300kg/cm 2 G pressure to afford the aimed compound useful as an intermediate for cosmetics and agricultural chemicals, etc. Furthermore, high activity can be stably maintained for a long period without accumulating by-products in a reactor and loss of rhodium can be reduced without requiring frequent regeneration of the catalyst, etc. n COPYRIGHT: (C)1989,JPO&Japio
priorityDate 1988-02-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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