http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H01168787-A

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filingDate 1987-12-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b8b3ae2f7fd703dbf0b08b00124d0664
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publicationDate 1989-07-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H01168787-A
titleOfInvention Plastic scintillator and its preparation
abstract PURPOSE: To obtain the title scintillator which is reliable even when used in a vacuum and has a high luminous efficiency, by the substitution of a polycyclic group for the phenyl group of a polymer having this group as its side chain to form a polymer having fluorescent molecules chemically bonded thereto. n CONSTITUTION: A polymer having a phenyl group as its side chain (e.g., polystyrene) is subjected to halogenation (e.g., bromination) of said groups in a solvent (e.g., CCl 4 ) in the presence of a catalyst (e.g., an iron powder). The resulting solution is filtered and dropped into an alcohol (e.g., CH 3 OH) to give a halogenated polymer. This polymer is mixed with a solvent (e.g., diethyl ether) and a catalyst (e.g., nickel diphenylphosphinoethane dichloride), and subjected to coupling reaction with a polycyclic Grignard compound (e.g., biphenylmagnesium bromide) for prescribed treatment, thus giving a scintillator comprising a polymer having repeating structural units of the formula (wherein A is a phenyl group substituted by a polycyclic group, e.g., a terphenyl group, and 0<x≤1). n COPYRIGHT: (C)1989,JPO&Japio
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-5205681-B2
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priorityDate 1987-12-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 35.