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filingDate 1987-05-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b7fa0f664c796882347403349d3c91a6
publicationDate 1989-05-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H01117856-A
titleOfInvention Novel 1-propenethiol derivative and production thereof
abstract NEW MATERIAL:The compound of formula I (X and Y are H or methyl; Y is methyl when X is H, and Y is H when X is methyl; A is thiol-protecting group eliminable with halogenation agent). n EXAMPLE: trans-1-Propenyl tritylsulfide. n USE: A synthetic intermediate for di(1-propenyl)disulfide useful as spices, antimicrobial agent, agricultural chemicals, pharmaceuticals, etc. The di(1- propenyl)disulfide is a drug-active component of garlic. n PREPARATION: The objective compound of formula I can be produced by isomerizing an allyl thiol derivative of formula II in a solvent (e.g., THF) in the presence of a base (e.g., potassium t-butoxide) at 10W100°C for 5W60min. The amount of the base is 1W3 equivalent based on the compound of formula II. n COPYRIGHT: (C)1989,JPO&Japio
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