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filingDate 2008-05-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2013-12-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2013-12-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-5361034-B2
titleOfInvention Ammoxidation catalyst for fluidized bed and method for producing acrylonitrile or methacrylonitrile using the same
abstract <P>PROBLEM TO BE SOLVED: To provide a catalyst which is capable of stably manufacturing acrylonitrile and the like with high yields for a long time under conditions with a reduced amount of ammonia that is excess to propylene and the like when acrylonitrile and the like are manufactured by the ammoxidation reaction using propylene and the like. <P>SOLUTION: The ammoxidation catalyst for the fluidized-bed is used for manufacturing acrylonitrile and the like by the reaction between propylene and the like, molecular oxygen and ammonia, has an element composition represented by general formula (1): Mo<SB>a</SB>Bi<SB>b</SB>Ce<SB>c</SB>Fe<SB>d</SB>E<SB>e</SB>J<SB>f</SB>G<SB>g</SB>L<SB>h</SB>O<SB>i</SB>, wherein E denotes Ni and the like, J denotes Mg and the like, G denotes Sb and the like, and L denotes K and the like and a-i each denotes the atomic ratio (specific numerical range) of each element, and is equipped with an oxide which satisfies the range of &alpha; and &beta;: 0.02&le;&alpha;&le;0.08, 0.08&le;&beta;&le;0.35 wherein &alpha; and &beta; are computed by formula (2); &alpha;=1.5(b+c)/(1.5d+e+f) and formula (3); &beta;=1.5d/(e+f) from the atomic ration of each element, and a carrier having the oxide supported. <P>COPYRIGHT: (C)2010,JPO&amp;INPIT
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