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filingDate 2007-12-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2013-08-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-5268018-B2
titleOfInvention Non-aqueous secondary battery composite graphite particles, negative electrode material containing the same, negative electrode and non-aqueous secondary battery
abstract A subject is to provide a nonaqueous secondary battery which is sufficiently low in charge/discharge irreversible capacity in initial cycling even when an active-material layer comprising a negative-electrode material and formed on a current collector has been densified for capacity increase. The subject has been accomplished with composite graphite particles for a nonaqueous secondary battery which comprise a composite of spherical graphite particles and a binder graphite and which at least satisfy any requirement selected from the group consisting of the following requirements (a) to (g): n(a) the composite graphite particles include composite graphite particles in which at least part of the spherical graphite particles is exposed at the surface thereof; (b) the composite graphite particles include composite graphite particles which have an imperfect laminate structure of the spherical graphite particles near the surface thereof; (c) when the median diameter of the spherical graphite particles and the median diameter of the composite graphite particles are expressed by a and b, respectively, then the ratio c=a/b is 0.93 or larger; (d) the composite graphite particles have a Raman R value of 0.15-0.25, an average degree of circularity of 0.85 or higher, a tap density of 0.87-1.25 g/cm 3 , and a BET specific surface area of 2.5-8 m 2 /g; (e) a volume of 0.01-2 µm pores as measured with a mercury porosimeter, is 0.05-1 mL/g; n(f) the amount of CO groups present on the surface normalized with the BET specific surface area is 1.15-5 µmol/m 2 ; and (g) when an electrode is produced by preparing a slurry using the composite graphite particles and a specific electrolytic solution is dropped onto the electrode, then the average time period required for the electrolytic solution to disappear completely from the electrode surface is 180 seconds or shorter.
priorityDate 2006-12-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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