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publicationDate 2021-11-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2021174656-A
titleOfInvention Polyolefin-based microporous membrane and its manufacturing method
abstract 【Task】 Providing a polyolefin-based microporous membrane with extremely low porosity, low shrinkage at high temperatures, excellent mechanical properties, excellent air permeability, and a thin film thickness, which is useful as a separator that enhances the safety of lithium-ion secondary batteries. do. SOLUTION: 30 to 65% by mass of a copolymer resin of 4-methyl-1-pentene and α-olefin having 3 or more carbon atoms, 25 to 50% by mass of ultrahigh molecular weight polyethylene, 1 to 15% by mass of polyethylene, and a diene system. A twin-screw extruder containing 10 to 45 parts by mass of a polyolefin resin mixture containing 0.1 to 2% by mass of a hydrogenated polymer and 0.5 to 5% by mass of a propylene-based elastomer resin, and 90 to 60 parts by mass of a plasticizer. To obtain a gel-like sheet molded product by supplying, melt-kneading, extruding from a die, and cooling to obtain a gel-like sheet molded product, biaxially stretching the gel-like sheet molded product to obtain a raw fabric A, one of the raw fabric A A part of the plasticizer is dissolved in a solvent to obtain the raw fabric B, and at least one of the raw fabric A and at least one of the raw fabric B are alternately stacked and bonded by applying heat and pressure. A method for producing a polyolefin-based microporous film, which comprises obtaining a single film and the weight ratio of the resin mixture to the plasticizer in the film is in the range of 50:50 to 70:30. [Selection diagram] None
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