http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2020119786-A

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filingDate 2019-01-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1ff4687b5ddfbb11a1a55dd6e351125a
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publicationDate 2020-08-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2020119786-A
titleOfInvention Nickel-manganese-cobalt-containing composite hydroxide, method for producing the same, positive electrode active material for lithium-ion secondary battery and method for producing the same, and lithium-ion secondary battery
abstract A positive electrode active material having a porous structure and a lithium nickel manganese cobalt-containing composite oxide with a high nickel ratio, which has improved durability and improved output characteristics. SOLUTION: Crystallization is divided into nucleation and particle growth, a first raw material aqueous solution is used for the first stage in a non-oxidizing atmosphere, and a second stage is an oxidizing atmosphere using a low nickel ratio second raw material aqueous solution. The third step is a first aqueous solution non-oxidizing atmosphere, the fourth step is a second aqueous solution oxidizing atmosphere, the fifth step is a first aqueous solution non-oxidizing atmosphere, and the sixth step is a second aqueous solution oxidizing atmosphere. The composite hydroxide is formed into a multilayer structure. The center portion 1, the high-density layer 3, and the outer shell layer 5 have a high nickel ratio, and the first to third low-density layers 2, 4 and 6 have a low nickel ratio, and a positive electrode active material using this composite hydroxide as a precursor The substance has an outer shell part, an agglomerate part electrically connected to the outer shell part, and a space part existing dispersedly between the agglomerates, and the primary particles have a surface layer part in which the nickel ratio is graded. Prepare [Selection diagram] Figure 1
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