| Predicate |
Object |
| classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-004
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-07
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-824 |
| classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D209-48
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D215-12
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D213-06
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-181
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D401-06
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D491-048
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D413-06
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B53-00
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D263-10 |
| classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-26
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D215-12
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-40
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C233-15
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C231-12
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D263-10 |
| filingDate |
2017-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate |
2019-05-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber |
JP-2019512519-A |
| titleOfInvention |
Pd (II) -Catalyzed Enantioselective .BETA.-Methylene C (sp3) -H Bond Activation |
| abstract |
Chiral Acetyl-Protected Aminoethyl Capable of Pd (II) -Catalyzed Enantioselective Arylation or Heteroarylation of Ubiquitous Prochiral .BETA.-Methylene CH Bonds of Aliphatic Amides Providing Alternative Cleavage to Build .BETA.-Chiral Centers Disclosed are quinoline (APAQ), pyridine and imidazoline ligands. Systematic formation of the ligand structure, instead of 5-membered chelation of these types of ligands with Pd (II), 6-membered chelation accelerates C (sp 3 ) -H activation, Reveals that it is important to achieve the enantioselectivity of quinoline and pyridine ligands. 【Selection chart】 None |
| priorityDate |
2016-03-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type |
http://data.epo.org/linked-data/def/patent/Publication |