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filingDate 2017-10-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2019-04-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2019063781-A
titleOfInvention Treatment method of waste acid generated in copper smelting
abstract PROBLEM TO BE SOLVED: To provide a method for treating waste acid capable of reducing the amount of cadmium to be repeated in the smelting process and reducing the carried-in water amount to suppress the drying cost. SOLUTION: A first sulfiding step of solid-liquid separation into a first sulfide residue and a first clear liquid after a sulfiding agent is added to a waste acid containing a heavy metal and a sulfuric acid component to sulfidize the heavy metal; A calcium-based neutralizing agent is added to the first clear liquid to form gypsum from the sulfuric acid, and then a gypsum manufacturing process for solid-liquid separation into gypsum and gypsum final solution, and a sulfurizing agent is added to the gypsum final solution The method further comprises a second sulfurizing step of solidifying solid-liquid separation into a second sulfide precipitate containing cadmium and a second clear liquid after sulfurizing the remaining heavy metal, wherein the cadmium sulfide grade of the second sulfide precipitate is 40% by mass If the cadmium content of the second sulfide precipitate is more than 50% by mass, the addition amount of the sulfiding agent is decreased in the second sulfiding step. . [Selected figure] Figure 1
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