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publicationDate 2017-11-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2017533214-A
titleOfInvention Method for removing water in situ from an oxidative esterification reaction using a linked reactor-distillation system
abstract The method for removing water from the oxidative esterification reactor includes (a) performing an oxidative esterification reaction in the reactor, (b) removing the crude product stream from the reactor, and (c) the crude product stream. Passing a first part of the product directly into the product recovery zone; (d) introducing a second part of the crude product stream into the distillation column to produce a top stream and a bottom stream; And b) recycling at least a portion of the bottom stream to the product recovery zone; and (f) recycling a recycle stream comprising at least a portion of the top stream to the reactor, Contains less than 1 weight percent (wt%) water based on the total weight of the recycle stream, the weight ratio of the first part to the second part is at least 1:10 and is recycled to the reactor The amount of recirculation flow that the reactor uses is less than 2.5 wt% Is an amount such that it has. [Selection] Figure 1
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