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filingDate 2014-03-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2016-04-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2016510814-A
titleOfInvention Method for reducing the formation of high-boiling compounds in the dehydrochlorination reaction of 1,1,1,3-tetrachloropropane
abstract The present invention relates to 1,1,3-trichloropropene (HCC-1240za) and / or 3,3,3-trichloropropene (HCC-1240zf) in dehydrochlorination of 1,1,1,3-tetrachloropropane (HCC-250fb). ) Concerning the method of improving the selectivity. In normal practice, 1,1,3-trichloropropene and / or 3,3,3-trichloropropene is produced using FeCl 3 as a catalyst for dehydrochlorination of HCC-250fb. The improvement in the present invention is that a mixture containing HCC-250fb produced by the reaction of CCl 4 and ethylene to produce HCC-250fb and a heavy component is used as a starting material. It includes the pentane isomer. These compounds reduce or eliminate the formation of unwanted high boiling compounds (HBCs). [Selection] Figure 1
priorityDate 2013-03-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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