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publicationDate 2015-11-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2015212423-A
titleOfInvention Extraction and separation method of light rare earth elements
abstract From light rare earth elements selected from lanthanum, cerium, praseodymium and neodymium, R1R2NCOCH2OCH2COOH (R1 and R2 are the same or different linear or branched alkyl groups, at least one of which has 6 or more carbon atoms. An organic phase containing a dialkyldiglycolamidic acid represented by an extractant as an extractant and an aqueous phase containing a light rare earth element, using an countercurrent multistage mixer settler to which an alkaline solution is added. When the element to be extracted is extracted from the organic phase by contact, the organic phase is contacted with the aqueous acid solution, and the element to be extracted is back-extracted and separated, the alkali amount of the alkali solution and the acid amount of the acid aqueous solution are The amount is 1.2 to 2.9 equivalents relative to the light rare earth element contained in the aqueous phase. [Effects] Light rare earth elements can be extracted and separated efficiently with a simpler process, and can be extracted and separated with a small-scale facility, thereby reducing the capital investment and running costs. Great value. [Selection] Figure 1
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