http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2015202434-A

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publicationDate 2015-11-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2015202434-A
titleOfInvention Production method of catalyst fine particles and carbon supported catalyst
abstract The present invention provides a catalyst fine particle and a carbon-supported catalyst having catalytic performance superior to conventional ones. Pd {111} in a reduction wave of a cyclic voltammogram in a first dispersion liquid in which palladium-containing fine particles having an average particle diameter of 3.0 nm to 6.0 nm are dispersed in an acidic solution. A potential applying step of applying a potential to the palladium-containing fine particles until the peak indicating the surface becomes larger than the peak indicating the Pd {110} surface or the Pd {100} surface, and the first dispersion and the copper-containing solution are mixed. Preparing a second dispersion, and applying a potential nobler than the redox potential of copper to the palladium-containing fine particles, thereby covering at least a part of the palladium-containing fine particles with copper; As a result of substituting copper and platinum by mixing a dispersion of platinum and a platinum-containing solution, white that covers at least a part of the palladium-containing fine particles with platinum is obtained. With a coating process, a manufacturing method of the catalyst particles. [Selection] Figure 7
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