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filingDate 2012-08-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2014-08-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2014521670-A
titleOfInvention Η5: η1-cyclopentadienylidene-phosphorane geometrically constrained complex of rare earth metals
abstract The present invention relates to a rare earth metal η 5 : η 1 -cyclopentadienylidene phosphorane geometrically constrained complex (abbreviated η 5 : η 1 -CpPC-CGC), a method for producing the same, and use thereof. The η 5 : η 1 -CpPC-CGC has the general formula (1) [wherein SE is Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb or Lu; X is independently of each other a monoanionic diorganoamide substituent, bistrimethylsilylamide substituent, halide substituent, alkyl substituent, aryl substituent, alkoxo substituent , Aryloxo substituent or alkylaluminate (AIR 4− ) substituent; L is a neutral ligand (PR 3 , NR 3 , pyridine), solvent molecule (THF, ether, DMF, DMSO, HMPT, Tetrahydropyran THP, tetrahydrothiofuran THT); R is alkyl having 1 to 10 carbon atoms or monocyclic or polycyclic having 6 to 20 carbon atoms R 1 and R 4 are independently of each other H or methyl; R 2 and R 3 are independently of each other H or methyl, or tertiary butyl, or together One substituted cycloalkyl group; R 5 , R 6 are methyl, n-butyl, tertiary butyl or phenyl; R 7 , R 8 are independently of each other H, trimethylsilyl, 1- Or alkyl having 10 carbon atoms or mono- or polycyclic aryl having 6 to 20 carbon atoms, and m is 0, 1, 2 or 3.
priorityDate 2011-08-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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