| abstract |
Provided is a trifluoromethylthiolation method using a hypervalent iodine ylide containing a trifluoromethanesulfonyl group. [Solution] By using a hypervalent iodine ylide reagent represented by the following general formula (1), a CF3S species is generated in the reaction system, and an organic compound containing a trifluoromethylthio group that is attracting attention in the fields of medicine, agricultural chemicals and materials. A method of synthesizing a compound. A process for producing a hypervalent iodine ylide represented by the above general formula (1), wherein (diacetoxyiodo) benzene is reacted with 1-phenyl-2-((trifluoromethane) sulfonyl) ethanone in the presence of a solvent. . [Selection figure] None |