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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F2-24
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filingDate 2013-05-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1f1ab6f0c7909e3bdf375ee58448a326
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_39675e9fc6e6b13c5d99789586f94817
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publicationDate 2014-12-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2014227422-A
titleOfInvention Vinyl acetate resin emulsion and method for producing the same
abstract [Problem] To provide a vinyl acetate resin emulsion having improved coating properties and roll cleaning properties, as well as excellent water resistance, heat resistance and initial adhesiveness. A vinyl acetate resin emulsion obtained by polymerizing at least one monomer in the presence of at least one polyvinyl alcohol resin using ethylene vinyl acetate copolymer resin emulsion as seed particles. The water elution rate of the film of the vinyl acetate copolymer resin emulsion is 10% or less, the monomer is vinyl acetate, the polyvinyl alcohol resin has a saponification degree of less than 90 mol% and an average polymerization degree of 2500. It is a polyvinyl alcohol resin other than the following polyvinyl alcohol resin, and the span calculation value defined by the following formula (1) is 1.0 or less. Span calculation value = | cumulative frequency% diameter A−cumulative frequency% diameter B | ÷ median diameter (μm) (1) (Here, the cumulative frequency% diameter A is the particle diameter (μm) of the vinyl acetate resin emulsion when the cumulative frequency during measurement is 10%, and the cumulative frequency% diameter B is 90% of the cumulative frequency during measurement. The particle diameter (μm) and median diameter of the vinyl acetate resin emulsion when the cumulative frequency becomes 50%, the particle diameter (μm) of the polyvinyl acetate resin emulsion when the cumulative frequency reaches 50%. Indicates absolute value.) [Selection figure] None
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