http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2013508326-A
Outgoing Links
Predicate | Object |
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classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-29 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-56 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-32 |
classificationIPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C47-228 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-27 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J27-128 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J27-125 |
filingDate | 2010-10-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2013-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-2013508326-A |
titleOfInvention | Process for preparing m- or p-substituted phenylalkanols by alkylation |
abstract | The subject of the present invention is that R 1 is bonded to the phenyl ring at the m-position or p-position and represents C 1 -C 5 alkyl, and R 2 , R 3 , R 4 and R 5 are independently of one another hydrogen. Or a process for preparing m- or p-substituted phenylalkanols of formula (I) representing methyl, wherein R 2 , R 3 , R 4 and R 5 have the meanings described in formula (I) An unsubstituted phenylalkanol of formula (II) is represented by the formula (III) R 1 -Hal (III), wherein R 1 has the meaning described in formula (I) and Hal represents halogen. Alkylation in the presence of a Friedel-Crafts catalyst together with the indicated C 1 -C 5 alkyl halide to give m- or p-alkyl substituted phenylalkanols of formula (I) and subsequently the reaction mixture is worked up. And the desired m in formula (I) Alternatively, the p-alkyl substituted phenylalkanol is separated and the remaining formed byproduct is returned to the reaction mixture and the byproduct is isomerized in the presence of Friedel-Crafts catalyst to produce the desired m- or p A process for preparing m- or p-substituted phenylalkanols of the formula (I), characterized in that they give rise to alkyl-substituted phenylalkanols. Oxidation or dehydrogenation from m- or p-alkyl substituted phenylalkanols of formula (I) can form the corresponding aldehydes as valuable products, which aldehydes have an interesting role as odorants and perfumes. play. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2013508331-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-7342868-B2 |
priorityDate | 2009-10-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 133.