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filingDate 2012-01-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2013-08-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2013147474-A
titleOfInvention Method for producing difluoroacetic acid ester
abstract The present invention provides a method capable of producing a difluoroacetate with high selectivity and high yield while suppressing the formation of by-products. SOLUTION: A 1,1,2,2-tetrafluoroethyl alkyl ether represented by a general formula: HCF 2 CF 2 OR (wherein R represents a lower alkyl group), an oxide and a general formula: A method of contacting with an acid catalyst in the presence of a lower alcohol represented by ROH (wherein R is the same as above), the reaction temperature is 20 to 60 ° C., and the amount of the acid catalyst used is 1 , 1,2,2-Tetrafluoroethyl alkyl ether, 0.1 to 0.5 moles per mole of the general formula: HCF 2 COOR (wherein R is the same as above) The manufacturing method of difluoroacetic acid ester represented by these. [Selection figure] None
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