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filingDate 2009-10-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2012-03-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2012507528-A
titleOfInvention Method for producing fluorinated ether, fluorinated ether, and use thereof
abstract The method for producing the fluorinated ether is in a polar aprotic solvent, Combining a fluorinated alcohol represented by the formula X—R f 1 CH 2 OH, a fluorinated sulfonate ester represented by the formula R f 2 CH 2 OS (═O) 2 R f 3 and a base; Obtaining a fluorinated ether represented by the formula Y—R f 1 CF 2 OCF 2 R f 2 —Y. R f 1 is selected from perfluorinated C 1 -C 10 alkylene groups having 1 to 10 carbon atoms, partially fluorinated C 1 -C 10 alkylene groups, and derivatives of the above alkylene groups having a chain heteroatom. Is done. X is, H, F, or HOCH 2 - represents a group. R f 2 is selected from perfluorinated C 1 -C 10 alkyl groups, partially fluorinated C 1 -C 10 alkyl groups, and derivatives of the above alkyl groups having a chain heteroatom. R f 3 is a C 1 -C 4 alkyl group. Y is, H, F, or R f 2 CH 2 OCH 2 - represents a group. Also disclosed are variants useful for preparing symmetrical fluorinated ethers. The present disclosure also provides fluorinated ethers that can be prepared according to this method. Also disclosed is the use of fluorinated ethers in various applications.
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