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filingDate 2009-08-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c6154493f8a36ab2ed135b83c35ae3a0
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publicationDate 2011-03-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2011042592-A
titleOfInvention Low Reaching Fluorous Multiphase Reaction Method
abstract [PROBLEMS] To provide a novel fluorous multiphase reaction method in which the reach of both solvent and catalyst is reduced in view of problems related to perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) and global warming. To do. A fluorous multiphase catalytic reaction method using at least a fluorous solvent and an organic solvent, wherein the catalyst is represented by the following general formula (1): M [N (SO 2 Rf 1 ) (SO 2 Rf 2 )] l (1) {In the formula, M is a metal selected from the group consisting of Hf, Sn, Yb, Y, Bi, La, and Sc, and Rf 1 independently of the following general formula (2): - (CF 2) m O [ CF (CF 3) CF 2 O] n CF 2 CF 3 (2) (Wherein m is an integer of 2 to 6 and n is an integer of 1 to 3), and Rf 2 is independently of each other Rf 1 or carbon number. 1 to 4 perfluoroalkyl groups, the total number of carbon atoms of Rf 1 and Rf 2 is 10 or more, and 1 represents the valence of the metal M. }, And a high-boiling perfluorohydrocarbon having a boiling point of 150 ° C. or higher, which may contain an oxygen atom and / or a nitrogen atom, is used as the fluorous solvent. The fluorous multiphase reaction method. [Selection figure] None
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