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filingDate 2008-03-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2010-06-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2010521538-A
titleOfInvention Method for producing water absorbent resin and use thereof
abstract The present invention relates to a method for producing a water-absorbent resin in which a hydrogel crosslinked polymer obtained by polymerization in the presence of an internal cross-linking agent is crushed in a crushing step and then dried, and polymerization is performed in a region where the internal cross-linking agent is large. In some cases, a method for producing a water-absorbent resin in which the amount of fine powder generated is reduced and a method for using the same are also provided. A monomer containing a carboxyl group-containing unsaturated monomer is reacted with an internal crosslinking agent (A) having two or more radically polymerizable unsaturated groups in one molecule and a carboxyl group in one molecule. And a step of polymerizing in the presence of a non-polymeric internal cross-linking agent (B) having two or more functional groups capable of forming an ester bond or an amide bond to obtain a water-containing gel-like cross-linked polymer. This is a production method comprising a step of crushing a hydrogel crosslinked polymer and a step of drying the obtained crushed product, and the amount of (A) used is 0 with respect to the carboxyl group-containing unsaturated monomer. 0.01 mol% or more and 0.2 mol% or less, and the molar ratio (B) / (A) is 0.01 or more and 1.8 or less. [Selection figure] None
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