http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2010013370-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_5f9bbbd98f2eaed32adaf0748ad97147 |
classificationIPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B57-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D303-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D301-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C12P41-00 |
filingDate | 2008-07-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8ccda149ff29236a719edd988463025c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d3534c53a061fe275072d5561b00a4a4 |
publicationDate | 2010-01-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-2010013370-A |
titleOfInvention | Zelumbon derivative and method for producing the same |
abstract | PROBLEM TO BE SOLVED: To provide a novel zerumbone derivative that can be used as a versatile chiral source and a production method thereof. Epoxidation of zerumbone with m-chloroperbenzoic acid in the presence of ethyl acetate yields a racemic 6,7-monoepoxy zerumbone, which racemic 6,7-mono. It was found that epoxy zerumbone was reacted in the presence of LiAlH 4 to obtain racemic 6,7-monoepoxy zerum ball. In addition, the obtained 6,7-monoepoxy zerumball has an optical activity by subjecting it to transesterification with isopropenyl acetate in the presence of lipase, so that it has optical activity and its acetate ester. (1S) was found to be obtained. Furthermore, it has been found that 6,7-monoepoxy zerumbone having novel optical activity can be obtained by oxidizing the (1R) -6,7-monoepoxy zerum ball having optical activity. [Selection figure] None |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-2360929-A2 |
priorityDate | 2008-07-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 59.