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publicationDate 2008-12-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2008546742-A
titleOfInvention Direct synthesis of alkylhalosilanes.
abstract A method for producing an alkylhalogenosilane by reacting an alkyl halide with a solid contact comprising silicon and a catalyst system, wherein the catalyst system comprises (α) a copper catalyst and (β) a group of additives for promotion And this accelerating additive group (β) is selected from additives β1, tin, tin-based compounds and mixtures thereof selected from metallic zinc, zinc-based compounds and mixtures thereof Additive β2, and optionally an additive β3 selected from cesium, potassium, rubidium, phosphorus, compounds derived from these metals / metalloids and mixtures thereof, the method comprising said copper Particle size in which the catalyst (α) is in the form of cuprous halide beads, the beads having a sphericity factor in the range of 0.6-1 and a D 50 value in the range of 50-1500 μm. Said production method characterized by having a normal distribution, a porous texture of 0.2 ml / g or less for pore diameters in the range of 0.1-10 μm, and a fluidity of 8 or more.
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