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publicationDate 2007-12-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2007335592-A
titleOfInvention Iron nitride magnetic powder, method for producing the same, and magnetic recording medium
abstract An iron nitride magnetic powder having significantly improved resistance (weather resistance) to deterioration with time of magnetic characteristics while maintaining excellent magnetic characteristics. A magnetic particle having an average particle diameter of 20 nm or less having a core mainly composed of Fe 16 N 2 phase and having an oxide phase derived from a metal Fe phase formed by reducing iron nitride on the outside of the core. An iron nitride-based magnetic powder that satisfies Δσs ≦ 0.8 × σs−30 in the relationship between the property index Δσs and the saturation magnetization σs. Here, Δσs = (σs−σs 1 ) / σs × 100, where σs 1 is saturation magnetization after the magnetic powder is held in an atmosphere of 60 ° C. and 90% RH for one week. In this powder, powder particles mainly composed of Fe 16 N 2 phase are exposed to a reducing gas so that a partial region from the surface of the particles is converted to a metallic Fe phase (gradual reduction treatment), and then exposed to an oxidizing gas to form the metallic Fe phase. It can obtain by making a partial area | region into the oxide phase from the surface (gradual oxidation process). [Selection] Figure 1
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