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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_42977f327db39d027537bde6093d0911
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publicationDate 2007-09-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2007224400-A
titleOfInvention Method for recovering electrolytic iron from aqueous iron chloride solution
abstract A step of leaching a copper raw material containing a copper sulfide mineral with chlorine, a step of reducing a leaching product solution, subjecting the reduction product solution to solvent extraction, separating and recovering copper to obtain an aqueous iron chloride solution, and iron chloride In a wet copper smelting method including a step of electrolytically collecting iron from an aqueous solution, a method for recovering electrolytic iron that can obtain an electrodeposit having a smooth surface state in the step of electrolytically collecting iron from the aqueous iron chloride solution is provided. In the step of electrolytically collecting iron from the aqueous iron chloride solution, a sulfurizing agent is added to the aqueous iron chloride solution and the oxidation-reduction potential (Ag / AgCl electrode standard) is controlled to -400 to -50 mV, By adjusting the pH to 3.0 to 4.5 by adding a pH adjuster, the lead contained in the iron chloride aqueous solution is precipitated and separated as a sulfide, and then the electrolytic extraction of iron is performed. . [Selection figure] None
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