http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2006520520-A

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publicationDate 2006-09-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2006520520-A
titleOfInvention New vanadium halide redox flow battery
abstract A pre-charged vanadium halide redox battery, a vanadium halide redox battery in a charge state selected from the group consisting of a zero charge state and a substantially zero charge state, and a fully charged vanadium halide redox cell Batteries and partially charged vanadium halide redox batteries are described. The pre-charged vanadium halide redox battery comprises: a positive half battery comprising a positive half battery solution comprising a halide electrolyte, vanadium (III) halide, and vanadium (IV) halide; a halide electrolyte; And a negative half-cell comprising a negative half-cell liquid comprising vanadium (III) halide and vanadium (N) halide, vanadium (III) halide in the positive and negative half-cell liquid, The amount of vanadium (IV) halide and halide ions is determined in the first charging step including the step of charging the pre-charging vanadium redox battery. Consists of zero charge state and nearly zero charge state, mainly consisting of vanadium halide (N) and mainly halogenated V (III) in the negative half-cell liquid. It has a state of charge selected from the group. The vanadium halide redox battery in a state of charge selected from the group consisting of the zero state of charge and substantially zero state of charge comprises a halide electrolyte and a vanadium halide that is primarily vanadium halide (N). A positive half-cell comprising a positive half-cell solution comprising: a negative half-cell comprising a halide electrolyte and a negative half-cell solution comprising a vanadium halide which is primarily vanadium (III) halide; The amount of vanadium halide (N) in the positive half-cell solution and the amount of vanadium (III) halide in the negative half-cell solution are such that the vanadium halide redox battery has zero charge state and substantially zero. In a state of charge selected from the group consisting of states of charge. The fully charged vanadium halide redox battery comprises a positive half battery solution comprising a halide electrolyte, a polyhalide complex, a vanadium (IV) halide, and a vanadium (V) halide. A negative half-cell comprising a negative half-cell solution comprising a halide electrolyte and vanadium (II) halide (molar concentration of vanadium (V) and polyhalide complex): ( The molar concentration of vanadium (II) halide) is equilibrated approximately stoichiometrically. The partially charged vanadium halide redox battery includes a positive half battery solution comprising a halide electrolyte, a polyhalide complex, a vanadium halide (IV), and a vanadium halide (V). A positive half-cell; and a negative half-cell comprising a negative half-cell solution comprising a halide electrolyte, vanadium (II) halide, and vanadium (III) halide (polyhalide complex and The number of moles of vanadium (V): (number of moles of vanadium (II) halide) is equilibrated approximately stoichiometrically.
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