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publicationDate 2006-08-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2006199681-A
titleOfInvention Method for producing acetic acid
abstract In the production of a carboxylic acid under a condition where the water concentration is low, the deactivation of a metal catalyst is suppressed to prevent a decrease in reaction rate, and the production of by-products is reduced. In the presence of a carbonylation catalyst system and a finite amount of water, an alcohol having n carbon atoms and carbon monoxide are continuously reacted, and a reaction mixture is continuously withdrawn from the reaction system 1 to obtain a distillation step ( In the method for producing a carboxylic acid, which is introduced into the distillation towers 3a and 3b) and separated into a high-boiling component and a low-boiling component containing a carboxylic acid having n + 1 carbon atoms, the monoxide contained in the liquid phase of the reaction system 1 The amount of carbon and / or hydrogen is adjusted to at least one of the following (i) and (ii). (i) The amount of carbon monoxide is at least 2 mmol per 1 MPa partial pressure of the reaction system and 1 kg of liquid phase weight. (ii) The amount of hydrogen is at least 50 mmol per 1 MPa partial pressure of hydrogen in the reaction system and 1 kg of liquid phase. [Selection] Figure 3
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