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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-716
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-303
filingDate 2004-12-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_258075284ba397d8e678336bff9f3042
publicationDate 2006-06-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2006160690-A
titleOfInvention Process for producing cis-2,3-disubstituted cyclopentanone
abstract Disclosed is a cis-2,3-disubstituted cyclopentanone that is particularly useful in the synthesis of jasmonic acid ester, which occupies an important position as a jasmine fragrance, and discharges harmful waste in a short process using a general-purpose device. Providing industrially manufactured technology. [Solution] A method for producing a cis-2,3-disubstituted cyclopentanone comprising the following five steps. 1st process which rearranges the compound of Formula (1) and manufactures the compound of Formula (2). Second step of producing a compound of formula (3) by isomerizing a compound of formula (2). Third step of producing a compound of formula (4) by alkylating the compound of formula (3). Fourth step of producing a compound of formula (5) by adding a malonic ester to a compound of formula (4) and decarboxylating. A fifth step of producing a cis-2,3-disubstituted cyclopentanone of formula (6) by hydrogenating the compound of formula (5). [Chemical 1] [Chemical 2] [Chemical 3] [Formula 4] [Chemical formula 5] [Chemical 6] [Selection figure] None
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