http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2006008589-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_9019c0ce5cb7b82c85e121f6cac86dce |
classificationIPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B53-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-042 |
filingDate | 2004-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_dca86f14154bf0fa4e03674833db4730 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6270b102e3058d811f100a4c6f1c5753 |
publicationDate | 2006-01-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-2006008589-A |
titleOfInvention | Process for producing optically active tertiary propargyl alcohol derivative |
abstract | The present invention provides a novel production method for producing an optically active tertiary propargyl alcohol derivative by asymmetrically adding a terminal alkyne to a ketone with high enantioselectivity. A method for producing an optically active tertiary propargyl alcohol derivative characterized in that an organozinc compound and a salen ligand having a binaphthyl skeleton are subjected to an asymmetric addition reaction of a terminal alkyne with a ketone. is there. The salen ligand having a binaphthyl skeleton is preferably a compound represented by the following formula (I). [Chemical 1] Wherein A is a divalent organic group; each R 1 is independently hydrogen or a monovalent organic group. ] [Selection figure] None |
priorityDate | 2004-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 62.