http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2005311083-A

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filingDate 2004-04-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f8c55a59efe80e3bdfccc2c5b9dd534f
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publicationDate 2005-11-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2005311083-A
titleOfInvention Manufacturing method of semiconductor device
abstract PROBLEM TO BE SOLVED: To suppress an electrolytic corrosion due to a photoelectric effect generated in a cleaning process after forming a metal film in a recess of an insulating film and to form a highly reliable metal film in the recess of the insulating film This manufacturing method is provided at low cost. A recess 7 is formed in an insulating film (SiOC film) 6, and a barrier metal film 8 and a copper film 9 serving as wiring are embedded in the recess 7. Next, after removing the excess copper film 9 and the barrier metal film 8 by using the CMP method, it is washed with a dilute aqueous ammonia solution and dried. Then, the copper film 9 is exposed to an oxygen atmosphere and oxidized to form a copper oxide 10 on the surface of the copper film 9. Then, it wash | cleans using the diluted oxalic acid aqueous solution. [Selection] Figure 5
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