| abstract |
An object of the present invention is to provide a novel dinuclear complex having a structure which is excellent in electron transfer in a specific direction, particularly has a structure excellent in electron transfer between binuclear atoms when irradiated with actinic rays such as light. A complex represented by the general formula (1), (L 0) l1 (X 0 ) l2 M 0 [(BL) m {M (L) n1 (X) n2} pm] q (1) (L 0 is a heteroconjugated ring having a binding functional group and represents a bidentate to tetradentate ligand capable of coordinating to a transition metal atom, and L is a heteroconjugated ring capable of coordinating to a transition metal atom. And X 0 and X each independently represent an anionic or neutral ligand having no heteroconjugated ring, and M 0 and M each represent an independent ligand Represents a transition metal atom, and BL represents a ligand having a moiety capable of coordinating with a plurality of transition metal atoms.) The moiety capable of coordinating with a plurality of transition metal atoms of BL has one heteroconjugated ring. not a coordination structure is, at least one having a coordination structure with a complex conjugate ring, coordinating one or more BL to M 0, all M 0 in coordination structure without a complex conjugate ring Coordinating binuclear complex. [Selection diagram] No selection diagram. |