http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2004339174-A

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-44
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-08
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filingDate 2003-05-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b85e683b000ccd5057a1ee374ecf53a5
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5016d1536f1027b70e3599bb8bf3ee34
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publicationDate 2004-12-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2004339174-A
titleOfInvention Method for esterifying carboxylic acid-containing mixture obtained from cyclohexane oxidation reaction solution and 1,6-hexanediol obtained from the ester mixture
abstract To obtain 1,6-hexanediol in a high yield from a carboxylic acid-containing mixture separated and recovered from a liquid-phase oxidation reaction solution of cyclohexane, and to monoesterify the carboxylic acid-containing mixture with a monoalcohol ester The aim is to develop a method. SOLUTION: When separating cyclohexanol and cyclohexanone from an oxidation reaction solution obtained by subjecting cyclohexane to liquid phase oxidation, and subjecting the recovered carboxylic acid-containing mixture to an esterification reaction, (1) In the presence of a strongly acidic solid catalyst having an acid strength of H 0 (Hammet's acidity function) of −3 or less, (2) gaseous lower monoalcohol; (3) bringing the above-mentioned carboxylic acid-containing mixture into countercurrent contact; This is solved by a method for esterifying a carboxylic acid-containing mixture, which is characterized in that the 1,6-hexanediol can be obtained in a high yield by hydrogenolyzing the esterified mixture obtained by the method. [Selection diagram] None
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-5428161-B2
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