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publicationDate 2004-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2004196869-A
titleOfInvention Method for producing porous polyimide-based fine particles
abstract The present invention provides a method for producing porous polyimide fine particles which is simple and has good reproducibility. A polyamic acid containing 0.5 to 80% by weight of an alkali metal salt with respect to the polyamic acid is 0.1 to 0.1%. the polymer solution was dissolved at a concentration of 15 wt% in a good solvent for the polyamic acid selected from an organic polar solvent, aliphatic solvents, alicyclic solvents, aromatic solvents, CS 2 and of two or more of these It is selected from a mixture, and injected into a poor solvent whose temperature is controlled at -20 ° C to 60 ° C, and the temperature of the poor solvent is controlled to have a particle size of 50 nm to 10000 nm, and the content and type of the alkali metal salt To form a porous polyamic acid fine particle having a pore diameter of 20 nm to 500 nm and a porosity of 0.1% to 30% controlled by the method described above, and then chemically or chemically imidizing the polyamic acid particle. A method for producing porous polyimide fine particles having the above-mentioned pore diameter and porosity by subjecting to thermal imidization after the formation. [Selection diagram] Fig. 1
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