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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-30
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D493-22
filingDate 2002-07-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5b4e5cec5127adac1badf3195c4608fa
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publicationDate 2004-02-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2004043384-A
titleOfInvention Gambierol production method
abstract An object of the present invention is to provide a method for synthesizing gambierol convergently under a relatively mild condition, which can be applied to total synthesis of gambierol. The following formula (I) is used. Embedded image The method for producing the Gambierol represented by the following formula (II) Embedded image In the presence of a Pd (PPh 3 ) 4 / CuCl / LiCl catalyst system, a Z-vinyl bromide compound represented by the following formula (III): Embedded image Reacts with Z-vinyltin represented by the following formula. [Selection diagram] Fig. 1
priorityDate 2002-07-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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