Predicate |
Object |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2603-40 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C17-093 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C23-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-083 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C46-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-143 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C303-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-676 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C49-665 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C49-683 |
classificationIPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C309-66 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-143 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-683 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-665 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-67 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C303-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C23-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C46-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C17-093 |
filingDate |
1999-11-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate |
2002-11-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
JP-2002538128-A |
titleOfInvention |
Synthesis of 4-ketocyclopentene and cyclopentadiene compounds |
abstract |
(57) [Summary]nPROBLEM TO BE SOLVED: To synthesize 4-ketocyclopentene and substituted 4-ketocyclopentene compounds which are compounds useful for synthesizing a cyclopentadienyl-containing metal complex useful for an addition polymerization catalyst composition.nSOLUTION: Starting from the corresponding 1-carbohydrocarbyloxy-2-keto-4-hydroxy-5-cyclopentene, reduction is followed by decarboxylation. The ketone then reduces the ketone to form an alcohol, displaces the hydroxyl function of the alcohol with a leaving group under displacement conditions, and deprotonates the resulting product under base-induced elimination conditions to give cyclopentadiene By forming a compound, it can be converted to a cyclopentadiene compound. Alternatively, functionalized cyclopentadienyl compounds can be produced without isolation of unsubstituted cyclopentadienyl compounds by combining a substitution step with an elimination and deprotonation step in a single unit operation. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-101098519-B1 |
priorityDate |
1999-03-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |