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publicationDate 2001-09-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2001514270-A
titleOfInvention Improved atom transfer radical polymerization
abstract (57) Abstract Upon exposure to visible light, atom transfer radical polymerization of vinyl monomers using transition metal compounds can result in accelerated polymerization and / or reduced requirements for transition metal compounds. Often there. A method of polymerizing a vinyl monomer by atom transfer radical polymerization using a first compound containing a transition metal and a second compound capable of radically transferring an atom or group to the first compound, A method is disclosed wherein the improvement comprises irradiating the liquid in which the polymerization takes place with visible light having an intensity of at least about 5 mW / cm 2 . The produced polymers are useful for molding resins and coatings.
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