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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D487-22
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/G01N21-19
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filingDate 2000-12-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_608a37c25cd4e07a5c8964c73af76321
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5a3a879a2d9bdf48a4231ec268eca63e
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_924f067581a9c2bed420da8ae681b3a1
publicationDate 2001-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2001220392-A
titleOfInvention How to determine the absolute configuration of a chiral compound
abstract (57) [Summary] [Problem] To provide a general-purpose, absolute configuration of a new chiral compound in which the kinds of basic groups to be bound can accurately and easily determine the absolute configuration of a chiral compound. Provide a decision method. The present invention has a structure of a porphyrin dimer cross-linked by a carbon chain, and extends from the carbon at a cross-linking position of one porphyrin ring of the dimer structure along the outer periphery of the porphyrin ring. Metal porphyrins with a bulky substituent on at least one of the second carbons more than an ethyl group, A chiral compound having an asymmetric carbon to which a basic group capable of coordinating to a metal of the other porphyrin ring in the dimer structure of the metal porphyrin or an asymmetric carbon at a position adjacent to the carbon atom to which the basic group is bonded And determining the absolute configuration of the chiral compound from the sign of the Cotton effect by circular dichroism spectrophotometric analysis.
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priorityDate 1999-12-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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