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filingDate 2000-01-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2001-07-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2001206870-A
titleOfInvention Method of oxidizing alkane
abstract (57) [Summary] [Problem] Molybdenum, vanadium supported on a carrier, Provided is a method capable of suppressing deterioration of the catalyst over time and allowing the operation to continue stably at a high selectivity when reacting alkanes with oxygen in a molecular state using an oxide catalyst containing niobium and antimony. thing. SOLUTION: Using an oxide catalyst supported on a carrier and containing molybdenum, vanadium, niobium and antimony, In a fluidized-bed reactor, when reacting an alkane having 3 to 6 carbon atoms with oxygen in a molecular state, the supply of the gas containing alkane and the gas containing oxygen requires gas flow from a nozzle for supplying the gas containing alkane, This is performed using each nozzle arranged so as to collide with a gas flow from a nozzle for supplying a gas containing oxygen, and the oxygen concentration in the gas at the outlet of the reactor is controlled to be 0.1% by volume or more. And react.
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