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filingDate 1999-12-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ed12aab8bb78f072bfc5228bb386abc8
publicationDate 2001-06-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2001158664-A
titleOfInvention Zirconia-based solid electrolyte having high conductivity and method for producing the same
abstract (57) [Summary] [PROBLEMS] To provide a method for producing a zirconia solid electrolyte, In the method of using alumina as a scavenger, the resistance of the grain boundary is reduced, but at the same time, since alumina slightly dissolves in the ZrO 2 grains, the intragranular resistance increases, and the overall conductivity does not improve much. It has not been put to practical use. SOLUTION: The composition is M x Zr 1-x O 2 (0.04 ≦ x ≦ 0.30, M is Y, Sc, Ca, or an element composed of a combination of two or more selected from the group consisting of zirconia-based oxides and 5 mol% or less of zircon (ZrSiO 4 ) or a zircon precursor. A zirconia-based solid electrolyte comprising: Silica contained as an impurity in the raw material zirconia-based oxide is converted to ZrSi. After the O 4 or ZrSiO 4 precursor, sintering is performed at a temperature of 1450 ° C. or more and 1750 ° C. or less, or 5 mol% or less of ZrSiO 4 is added to a raw material zirconia-based oxide; Alternatively, the ZrSiO 4 composition of 5 mol% or less After adding rO 2 and SiO 2 , 1450 ° C. or more 1750 A zirconia-based solid electrolyte is produced by sintering at a temperature of not more than ℃.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2003089576-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2018080963-A
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