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publicationDate 2001-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2001089896-A
titleOfInvention Plating method, plating solution, semiconductor device and method of manufacturing the same
abstract (57) Abstract: In a copper plating process for a semiconductor, there is provided an additive and a film forming method in which copper plating is preferentially advanced in a groove having a width of 1 μm or less or a hole having a diameter of 1 μm or less and voids are not generated. . In a process of forming a film on a substrate having a groove having a height h and a width w or a hole having a radius w, a diffusion coefficient D of a material (additive) which inhibits film formation by being added is added. When the ratio of [m 2 / s] and the reaction rate κ [m / s] of adsorption or consumption on the surface is D / κ, an additive and a film forming process that simultaneously satisfy the following two inequalities are used. 0.005 × h 2 /w<D/κ<0.5×h 2 / w, 0.0 1 <Θ ≦ 0.7 Here, Θ is (film deposition rate with additive) / (film deposition rate without additive) at the same plating potential.
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