http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2000288399-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_046e16bd6918ef3cd62184605b15a413 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-0266 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-645 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-821 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2457 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-0053 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D315-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D305-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D315-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-50 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-24 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B53-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-00 |
filingDate | 1999-03-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_11b54c1890eb82b072e54264ea3e2d06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2e3fa16c1138b3f751b2a38b451cf63c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d0b5db3fe92b4ef6a33ae6bc40774aca http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f679d3ea465f344842663e7f42d19a2e |
publicationDate | 2000-10-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-2000288399-A |
titleOfInvention | Ruthenium-optically active phosphine complex mixture, its preparation and asymmetric hydrogenation catalyst using the same |
abstract | (57) Abstract: The present invention provides a novel ruthenium-optically active phosphine complex mixture useful as a catalyst for an organic synthesis reaction. This mixture is a particularly useful asymmetric hydrogenation catalyst for the production of optically active 4-methyl-2-oxetanone. SOLUTION: The following formulas (1), (2) and (3), [Ru (R 1 -SEGPHOS) (sol) 4 ] I 2 ... (1) [Ru (R 1 -SEGPHOS) (sol ) 4 ] I (anion) ・ ・ ・ (2) [RuI (R 1 -SEGPHOS) (sol) 3 ] (anion) ・ ・ ・ (3) 中 wherein sol is a nitrile solvent and R 1- SEGPHOS is given by equation (4) (Here, R 1 has a substituent selected from the group consisting of a lower alkyl group having 1 to 4 carbon atoms, a lower alkoxy group having 1 to 4 carbon atoms, a lower alkylamino group having 1 to 4 carbon atoms, and a halogen atom. Represents an aryl group or a cycloalkyl group having 3 to 8 carbon atoms which may be optionally present), and anion represents a perfluoroalkylsulfonyl anion. A mixture of ruthenium and an optically active phosphine complex, characterized by containing a complex of the above, a process for producing the same, and an asymmetric hydrogenation catalyst comprising the mixture. |
priorityDate | 1999-03-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 135.