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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7525a353cb2508846669d6a5090d54a6
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publicationDate 2000-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2000178023-A
titleOfInvention Nitrogen-containing mixed salt from nitric acid and ammonia containing liquid and its recovery method
abstract PROBLEM TO BE SOLVED: To simultaneously treat and remove nitric acid and ammonia in wastewater by an inexpensive method, to crystallize nitric acid and ammonia without decomposing them, and to improve the hygroscopicity of crystals. To be reused as nitrogen fertilizer. SOLUTION: The pH of the waste water adjusted to pH 4 to 7 with sulfuric acid. An adjustment step, a preconcentration step of evaporating and concentrating the adjusted wastewater to such an extent that it does not crystallize, a nitrogen grade stabilization step of suppressing the composition fluctuation of the concentrated wastewater by a cushion tank, etc., and a crystallization step of evaporating and concentrating the stable wastewater. A crystal recovery step of recovering a mixed salt crystal from the mixed concentrated liquid by filtration, preferably, Further, a nitrogen-containing mixed salt is recovered by a method comprising a step of adding a surface treating agent such as a surfactant to the recovered mixed salt crystal to improve the hygroscopicity. Then, a nitrogen-containing mixed salt crystal having a water content of 10% by weight or less, an average particle diameter of 100 μm or more, and good handleability and low hygroscopicity recovered by this method is used as a nitrogen fertilizer.
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2010120815-A
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