http://rdf.ncbi.nlm.nih.gov/pubchem/patent/IT-1251464-B
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_03ade04c304817cb15fe4aac06476101 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F- |
filingDate | 1991-07-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 1995-05-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1726c2763743a4ba738a384ddba152c8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1ac61944ef3580073a6e7114c9cf0624 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_588037ef13ff4cb3f0dfc1db61e818b0 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9878f8910e1f6ef478ad461e76730836 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e92b1f3b865ba4553dc08fe0b8247079 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cc3714ca7401152cdf163007030f3ab6 |
publicationDate | 1995-05-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | IT-1251464-B |
titleOfInvention | PRODUCTION OF VANADIUM BIS-ARENI FROM VANADIUM OXYCHLORIDE |
abstract | A process is described for the preparation of a bis-arene vanadium, [V (arene) 2], starting from vanadium oxychloride, metallic aluminum, aluminum trichloride and an arene, in which: - (a) are brought into contact , in a first reaction stage, vanadium oxychloride (VOCl3), active metallic aluminum and aluminum trichloride, with a molar ratio between aluminum trichloride and vanadium oxychloride equal to or greater than 2 and with a molar ratio between metallic aluminum and vanadium oxychloride equal to or greater than 2, in a liquid arene, to form the complex [V (arene) 2] + [AlCl4]; - (b) a liquid cyclic or alicyclic ether is added to the product of the reaction of step (a) to reduce [V (arenas) 2] + in [V (arenas) 2]; and - (c) vanadium bis-arene [V (arene) 2] is recovered from the product of the reaction of step (b). The vanadium arenes thus obtained are useful in the preparation of olefin polymerization catalysts. |
priorityDate | 1991-07-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 28.