http://rdf.ncbi.nlm.nih.gov/pubchem/patent/IT-1027332-B
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_16890954fa97fa1ea88523e23b283152 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C251-88 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C249-16 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C- http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J27-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-77 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D- |
filingDate | 1975-01-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 1978-11-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1978-11-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | IT-1027332-B |
titleOfInvention | PROCEDURE FOR THE SYNTHESIS OF HYDRAZINE DERIVATIVES |
abstract | Ammonia and aldehydes or ketones are selectively oxidized by hydrogen peroxide to the corresponding azines when they are reacted in the presence of both (a) an amide of a carboxylic acid having a pK greater than about 4.3 and (b) a co-catalyst having the general formula H-X-Y=Z, wherein H is hydrogen, X and Z are each an atom of oxygen or nitrogen and Y is an atom of carbon, nitrogen, arsenic, antimony, phosphorus, sulfur, selenium or tellurium; the atoms of X, Y, and Z carrying other substituents necessary to obey the rules of valence. Preferred co-catalysts include di(alkali metal) hydrogen phosphates, lower dialkyl phosphate esters, bicarbonates and p-toluene sulfonic acid. When 1 DEG or 2 DEG amines are also present, hydrazones are also formed along with the azines. Uses of the resultant products include their hydrolysis to hydrazines with recycling of aldehyde or ketone. |
priorityDate | 1974-02-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 45.