http://rdf.ncbi.nlm.nih.gov/pubchem/patent/IN-2014DN08854-A

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publicationDate 2015-05-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber IN-2014DN08854-A
abstract Provided is an improved method for continuously producing a high molecular weight polycarbonate resin by subjecting an aromatic polycarbonate prepolymer and an aliphatic diol compound to a molecular weight increasing linking reaction whereby it becomes possible to allow an aliphatic diol compound having a relatively low boiling point to contribute to the molecular weight increasing linking reaction with high efficiency and it also becomes possible to produce a high molecular weight polycarbonate resin having excellent quality in an economically advantageous manner. The method comprises subjecting an aromatic dihydroxy compound and a diester carbonate to a polycondensation reaction to produce an aromatic polycarbonate prepolymer adding an aliphatic diol compound having an aliphatic group capable of binding to a terminal hydroxy group to the aromatic polycarbonate prepolymer to produce a prepolymer mixture and subjecting the prepolymer mixture to a molecular weight increasing linking reaction under pressure reduced conditions wherein the aliphatic diol compound is added under a pressure of higher than 200 torr and subsequently the prepolymer mixture is subjected to the molecular weight increasing linking reaction before the concentration of a terminal hydroxy group of the aromatic polycarbonate prepolymer in the prepolymer mixture reaches 2000 ppm.
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