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filingDate 1987-08-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1991-06-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber HU-T55838-A
titleOfInvention Working up chrome-tanned waste leather
abstract Chrome cured leather waste is processed at room temp. and atmospheric pressure at pH 12-13 with a potassium carbonate contg. sodium-carbonate soln.. Water for prepn. of this soln. is deionised or at least calcium-free. Hydrogen-peroxide is added while pH is maintained. The protein suspension is sepd. from the soln. by filtration and pptd. chrome is removed as Cr(OH)3 and Cr(SO4)3 from the filtrate following the addn. of FeSO4. Chromium-free water is opt. recirculated to the presoaking stage. Collagen is regenerated by sulphuric acid hydrolysis and remaining Cr(VI) ions are reduced by sodium pyrosulphite. The soln. is filtered and chrome-alum KCr(SO4)2 formed is opt. returned into the curing cycle. - The protein component washed by water and dried, has several direct uses. The chromium content of the protein may be reduced to less than 1ppm by dialysis after sulphuric acid treatment and water washing and by pptn. with Na2SO4. Further purification is possible by repetition of this process. (-pp Dwg.No.0/0)
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