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assignee http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c7ad58d3c0b071069a8ee0cb8c8ba2e8
classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D327-06
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D307-74
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D405-12
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D327-06
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D405-12
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D307-74
filingDate 1963-11-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1965-05-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-992166-A
titleOfInvention New 5-nitro-furfurylidene derivatives
abstract The invention comprises compounds of the formula <FORM:0992166/C2/1> wherein R represents a hydrogen atom or from 1 to 4 alkyl radicals, each containing up to 4 carbon atoms; and a process for their preparation comprising reacting a 4-amino-tetrahydro-1,4-thiazine-1,1-dioxide with 5-nitro-furfural, the reaction preferably being carried out in an organic solvent medium in which both starting components are soluble and in which the desired end product is insoluble. 4 - Amino - 3 - methyl - tetrahydro - 1,4 - thiazine-1,1-dioxide is prepared by reacting 2-mercapto-ethanol with propylene oxide in the presence of KOH, distilling the resulting 2 - hydroxyethyl - 2 - hydroxypropyl sulphide over p-toluene sulphonic acid or KHSO4 at atmospheric pressure to produce 2-methyl-1,4-oxathiane, oxidizing this compound with H2O2 in acetic acid, and reacting the thus obtained 2 - methyl - 1,4 - oxathiane - 4,4 - dioxide with excess hydrazine. The corresponding 2-ethyl compound is prepared in an analogous manner. Specification 889,068 is referred to.
priorityDate 1962-11-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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