http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-985594-A

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assignee http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_47becd0bad1e8c65826be1edac09d306
classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F210-00
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F210-00
filingDate 1963-02-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1965-03-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-985594-A
titleOfInvention Process for the preparation of olefinic copolymers
abstract Linear amorphous copolymers of propylene or butene-1 and ethylene are made by effecting the polymerization of the monomeric mix in the liquid phase at a temperature of 0 DEG to - 80 DEG C., in the presence of a catalyst obtained by contacting an addition complex of a vanadium halide with a "Lewis base" with a dialkyl aluminium halide, by maintaining in the liquid phase a molar ratio between propylene:ethylene of at least 4:1, or of butene: ethylene of at least 25:1. The polymerization may be carried out in bulk or in the presence of a halogenated or non-halogenated hydrocarbon diluent. The term "Lewis base" means aliphatic ethers, cyclic ethers, tert-amines, or heterocyclic nitrogen bases, e.g. diethyl or dipropyl ether, diethoxyethane, tetrahydrofuran, dioxan, trimethylamine, methyl-diethylamine, pyridine, or quinoline. The vanadium halide may be vanadium tetra-, or trichloride, or vanadyl trichloride. The catalyst may be preformed, but is preferably formed in the presence of the monomers. The process may be effected continuously and the product recovered by known methods.
priorityDate 1960-10-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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